Effect of Exhaust Gas Flow Velocity on the Chemisorption of Nitrogen Oxides
DOI:
https://doi.org/10.17721/fujcV14I1P151-158Keywords:
absorption, NOx neutralization, bubbling, exhaust gas flow velocity, diesel enginesAbstract
This study investigates wet scrubbing of diesel exhaust gases for NOx removal, as NOx is one of the major pollutants associated with diesel engine operation. Chemical absorption of NOx was achieved through the interaction of exhaust gases with aqueous absorbent solutions (KMnO₄ + HNO₃, KMnO₄ + H₂SO₃, CO(NH₂)₂ + SnCl₂, and water) under bubbling conditions. The dependence of NOx neutralization efficiency on the flow velocity of treated exhaust gases was established. The proposed relationship, along with the methodology developed on its basis, enables the evaluation of the performance of chemical absorbents in the wet neutralization of NOx from diesel exhaust gases, taking into account hydrodynamic and gas–liquid interaction effects.
References
Thakur P. Diesel Exhaust Control. Advanced Mine Ventilation 2019:157-187. https://doi.org/10.1016/b978-0-08-100457-9.00011-0
Fan Z, Lin L. Exposure Science: Contaminant Mixtures. Encyclopedia of Environmental Health 2011:645-656. https://doi.org/10.1016/b978-0-444-52272-6.00122-7
Reşitoğlu İ, Altinişik K, Keskin A. The pollutant emissions from diesel-engine vehicles and exhaust aftertreatment systems. Clean Technologies and Environmental Policy 2014;17(1):15-27. https://doi.org/10.1007/s10098-014-0793-9
Dobrzyńska E, Szewczyńska M, Pośniak M, Szczotka A, Puchałka B, Woodburn J. Exhaust emissions from diesel engines fueled by different blends with the addition of nanomodifiers and hydrotreated vegetable oil HVO. Environmental Pollution 2020;259:113772. https://doi.org/10.1016/j.envpol.2019.113772
Sassykova L, Aubakirov Y, Sendilvelan S, Tashmukhambetova Z, Faizullaeva M, Bhaskar K, Batyrbayeva A, Ryskaliyeva R, Tyussyupova B, Zhakupova A, Sarybayev M. The Main Components of Vehicle Exhaust Gases and Their Effective Catalytic Neutralization. Oriental Journal of Chemistry 2019;35(1):110-127. https://doi.org/10.13005/ojc/350112
Shcheklein S, Dubinin A. Analysis of nitrogen oxide emissions from modern vehicles using hydrogen or other natural and synthetic fuels in combustion chamber. International Journal of Hydrogen Energy 2020;45(1):1151-1157. https://doi.org/10.1016/j.ijhydene.2019.10.206
Sun J, Caton J, Jacobs T. Oxides of nitrogen emissions from biodiesel-fuelled diesel engines. Progress in Energy and Combustion Science 2010;36(6):677-695. https://doi.org/10.1016/j.pecs.2010.02.004
Chong H, Park Y, Kwon S, Hong Y. Analysis of real driving gaseous emissions from light-duty diesel vehicles. Transportation Research Part D: Transport and Environment 2018;65:485-499. https://doi.org/10.1016/j.trd.2018.09.015
Miller B. Nitrogen oxides formation and control. Fossil Fuel Emissions Control Technologies 2015:243-280. https://doi.org/10.1016/b978-0-12-801566-7.00005-1
Reid H, Aherne J. Staggering reductions in atmospheric nitrogen dioxide across Canada in response to legislated transportation emissions reductions. Atmospheric Environment 2016;146:252-260. https://doi.org/10.1016/j.atmosenv.2016.09.032
Mei X, Xin Y, Zhang Y, Nie W, Zhang Z, Lu P, Zhang Z, Chen G, Zhang J. Electrification-Enhanced Low-Temperature NOx Storage–Reduction on Pt and K Co-Supported Antimony-Doped Tin Oxides. Environmental Science & Technology 2023;57(49):20905-20914. https://doi.org/10.1021/acs.est.3c05354
Shukla M, Chauhan B, Verma S, Dhar A. Catalytic Direct Decomposition of NOx Using Non-Noble Metal Catalysts. Solids 2022;3(4):665-683. https://doi.org/10.3390/solids3040041
Zhao J, Sun J, Meng X, Li Z. Recent Advances in Vehicle Exhaust Treatment with Photocatalytic Technology. Catalysts 2022;12(9):1051. https://doi.org/10.3390/catal12091051
Jo H, Ko A, Jang J, Lim O. Study on Rates of NH3 Adsorption and Desorption in SCR on Various Engine Operation Conditions. Sustainability 2023;15(19):14468. https://doi.org/10.3390/su151914468
Li X, Ren S, Chen Z, Wang M, Chen L, Chen H, Yin X. A Review of Mn-Based Catalysts for Abating NOx and CO in Low-Temperature Flue Gas: Performance and Mechanisms. Molecules 2023;28(19):6885. https://doi.org/10.3390/molecules28196885
Gan L, Liu Y, Ye P, Niu H, Li K. Reaction Mechanism for the Removal of NOx by Wet Scrubbing Using Urea Solution: Determination of Main and Side Reaction Paths. Molecules 2022;28(1):162. https://doi.org/10.3390/molecules28010162
Goto T, Ohyama R. An experimental study on neutralization of non-thermal plasma oxidized diesel engine combustion exhaust NOx gases with hydrated lime filter. The 17th Annual Meeting of the IEEE Lasers and Electro-Optics Society, 2004. LEOS 2004. 2004:114-117. https://doi.org/10.1109/ceidp.2004.1364202
Seo H, Jeong R, Boo J, Song J, Boo J. Study on Chemical Removal of Nitric Oxide (NO) as a Main Cause of Fine Dust (Air Pollution) and Acid Rain. Applied Science and Convergence Technology 2017;26(6):218-222. https://doi.org/10.5757/asct.2017.26.6.218
Pan S, He K, Lin K, Fan C, Chang C. Addressing nitrogenous gases from croplands toward low-emission agriculture. npj Climate and Atmospheric Science 2022;5(1):43. https://doi.org/10.1038/s41612-022-00265-3
Guo X, Chen L, Zheng R, Zhang K, Qiu Y, Yue H. Differences in Soil Nitrogen Availability and Transformation in Relation to Land Use in the Napahai Wetland, Southwest China. Journal of Soil Science and Plant Nutrition 2019;19(1):92-97. https://doi.org/10.1007/s42729-019-0013-0
Ladan S, Jacinthe P. Nitrogen availability and early corn growth on plowed and no-till soils amended with different types of cover crops. Journal of soil science and plant nutrition 2017;17(1):74–90. https://doi.org/10.4067/s0718-95162017005000006
Martínez J, Galantini J, Duval M. Contribution of nitrogen mineralization indices, labile organic matter and soil properties in predicting nitrogen mineralization. Journal of soil science and plant nutrition 2018;18(1):73–89. https://doi.org/10.4067/s0718-95162018005000401
Saggar S, Jha N, Deslippe J, Bolan N, Luo J, Giltrap D, Kim D, Zaman M, Tillman R. Denitrification and N2O:N2 production in temperate grasslands: Processes, measurements, modelling and mitigating negative impacts. Science of The Total Environment 2013;465:173-195. https://doi.org/10.1016/j.scitotenv.2012.11.050
Ali M, Hussain I, Mehmud I, Umair M, Hu S, Sharif H. Recent Breakthroughs and Advancements in NOx and SOx Reduction Using Nanomaterials-Based Technologies: A State-of-the-Art Review. Nanomaterials 2021;11(12):3301. https://doi.org/10.3390/nano11123301
Martinovic F, Castoldi L, Deorsola F. Aftertreatment Technologies for Diesel Engines: An Overview of the Combined Systems. Catalysts 2021;11(6):653. https://doi.org/10.3390/catal11060653
Zhu Z, Xu B. Purification Technologies for NOx Removal from Flue Gas: A Review. Separations 2022;9(10):307. https://doi.org/10.3390/separations9100307
Gooneh-Farahani S, Anbia M. Strategies to Reduce NOx Emissions from Flue Gas: Trends and Prospects. Water, Air, & Soil Pollution 2025;236(11):718. https://doi.org/10.1007/s11270-025-08373-5
Sun Y, Li M, Zhu T, Li X, Gao Y, Fu J. Removal of NOx and PM from Non-Road Mobile Machinery by the Combination of Ozone Oxidation and Venturi Scrubbing. Processes 2025;13(11):3525. https://doi.org/10.3390/pr13113525
Semykin VM. Analysis of the Application Area of Liquid-Phase Neutralization of Diesel Exhaust Gases. Automobile Transport: Collection of Scientific Papers of Kharkiv National Automobile and Highway University 2008;22:128–130.
Kudryash AP, Kireeva VN, Semykin VM. Neutralization of nitrogen oxides in diesel exhaust gases under steady-state conditions. Bulletin of Kharkiv State Polytechnic University. Internal Combustion Engines 1999;58:139–146.
Ramm VM. Gas Absorption. Moscow: Chemistry 1976;656.
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