A Review on Anticorrosion Activity of 5-Chloroistin Derivatives on Mild Steel in Acidic Media

Authors

  • Zineb Tribak Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology, Sidi Mohamed Ben Abdellah University, Fez Morocco
  • Mohammed Khalid Skalli Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology, Sidi Mohamed Ben Abdellah University, Fez Morocco
  • Omar Senhaji Biomolecular and Macromolecular Chemistry Team, Faculty of Sciences , Moulay Ismail University, Meknes Morocco
  • Amal Haoudi Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology, Sidi Mohamed Ben Abdellah University, Fez Morocco
  • Youssef Kandri Rodi Laboratory of Applied Organic Chemistry, Faculty of Sciences and Technology, Sidi Mohamed Ben Abdellah University, Fez Morocco

DOI:

https://doi.org/10.17721/fujcV14I1P141-150

Keywords:

5-Chloroisatin derivatives, mild steel, acid, Corrosion inhibition efficiency, SEM

Abstract

In an acidic environment, the corrosion phenomenon deteriorates mild steel, hence the organic corrosion inhibitors could figure out this problem. This paper gives a comprehensive review details an investigation on the protection of mild steel in acidic media by adding 5-Chloroisatin derivatives as organic inhibitors at different concentrations analyzed by weight loss, electrochemical impedance spectroscopy, Tafel polarization and scanning electron microscope (SEM). The main results have shown that the 1-allyl-5-chloro-indoline-2,3-dione (TZACI), 5-chloro-1-octylindoline-2,3-dione (TZCOI) and 5-chloro-1-(2-(dimethylamino) ethyl) indoline-2,3-dione (TZCDI) are excellent corrosion inhibitors of mild steel in acid medium with an efficiency higher than 90%. The inhibitors adsorptions on the mild steel surface follow the Langmuir adsorption isotherm.

References

Fouda A, Rashwan S, Emam A, El-Morsy F. Corrosion Inhibition of Zinc in Acid Medium using some Novel Organic Compounds. International Journal of Electrochemical Science 2018;13(4):3719-3744. https://doi.org/10.20964/2018.04.23

Chaitra T, Mohana K, Tandon H. Comparative study of Levofloxacin and its amide derivative as efficient water soluble inhibitors for mild steel corrosion in hydrochloric acid solution. International Journal of Industrial Chemistry 2016;8(1):1-15. https://doi.org/10.1007/s40090-016-0083-y

Fouda A, Diab M, Fathy S. Role of Some Organic Compounds as Corrosion Inhibitors for 316L Stainless Steel in 1 M HCl. International Journal of Electrochemical Science 2017;12(1):347-362. https://doi.org/10.20964/2017.01.60

Guo L, Kaya S, Obot I, Zheng X, Qiang Y. Toward understanding the anticorrosive mechanism of some thiourea derivatives for carbon steel corrosion: A combined DFT and molecular dynamics investigation. Journal of Colloid and Interface Science 2017;506:478-485. https://doi.org/10.1016/j.jcis.2017.07.082

Tribak Z, Rodi YK, Haoudi A. Cycloaddition 1,3-Dipolaire Des Derives De La 5-Chloro- 1h-Indole-2,3 Dione :Vers De Nouvelles Isoxazolines Et Spirodioxazolines. Jmarchimheterocycl 2017;16:58–65.

Skalli M, Senhaji O, Rodi Y. Synthesis of 1,2,3-Triazole 5-Chloroisatin Derivatives via Copper-Catalyzed 1,3-Dipolar Cycloaddition Reactions. International Journal of Advanced Engineering, Management and Science 2017;3(8):837-841. https://doi.org/10.24001/ijaems.3.8.3

Tribak Z, Ghibate R, Skalli M, Rodi Y, Mrani D, Aouniti A, Hammouti B, Senhaji O. Synthesis and Characterization of a New Cationic Surfactant Derived from 5-Chloro-1H-indole-2,3-dione In Aqueous Systems. International Journal of Engineering Research and Applications 2017;07(04):04-08. https://doi.org/10.9790/9622-0704010408

Tribak Z, Skalli M, Senhaji O, Rodi Y. Syntheses and Characterizations of Some New N-alkyl, Isoxazole and Dioxazole Derivatives of 5-Chloroisatin. International Journal of Advanced Engineering, Management and Science 2017;3(8):882-885. https://doi.org/10.24001/ijaems.3.8.11

Tribak Z, Skalli MK, Senhaji O. Experimental and Theoretical DFT Study on Synthesis of Novel 5-Chloroisatin Derivatives via 1, 3-Dipolar Cycloaddition Reactions between Allyl-5-chloroindoline-2, 3-dione and 4-Chlorobenzaldoxime. International Journal of Applied Chemistry 2017;4:2–7.

Tribak Z, Skalli MK, Senhaji O. DFT Study and Synthesis of New 1, 2, 3-triazoles Obtained by 1, 3-Dipolar Cycloaddition Derived from 5-chloro-1-(prop-2-yn-1-yl)indoline-2, 3-dione. International Journal of Science and Research (IJSR) 2017;6(7):1069-1074. https://doi.org/10.21275/12071705

Williams J, Drach J, Townsend L. Synthesis and Antiviral Activity of Some 2-Substituted 3-Formyl-and 3-Cyano-5,6-Dichloroindole Nucleosides. Nucleosides, Nucleotides & Nucleic Acids 2005;24(10-12):1613-1626. https://doi.org/10.1080/15257770500265836

Tribak Z, Skalli M, Haoudi A, Rodi Y, Senhaji O, Essassi E. Cyclocondensation, Characterization and Antibacterial Activities of Novel 5-Chloro-1HIndole-2,3-Dione Derivatives. Journal of Applied Microbiology and Biochemistry 2018;02(02):1–4. https://doi.org/10.21767/2576-1412.100023

Tribak Z, Amin O, Skalli M, Senhaji O, Rodi Y, Iraqui M. Synthesis, Characterization, and Antibacterial Activity of Some Novel 5-Chloroisatin Derivatives. International Journal of Engineering Research and Applications 2017;07(06):66-70. https://doi.org/10.9790/9622-0706046670

Tribak Z, El Amin O, Skalli M, Senhaji O, Rodi Y, Iraqui M. N-alkylation methods, Characterization and Evaluation of antibacterial activity of some Novel 5-Chloroisatin Derivative. International Journal of Engineering Research and Applications 2017;07(06):21-24. https://doi.org/10.9790/9622-0706052124

Bhati S, Kumar A. Synthesis of new substituted azetidinoyl and thiazolidinoyl-1,3,4-thiadiazino (6,5-b) indoles as promising anti-inflammatory agents. European Journal of Medicinal Chemistry 2008;43(11):2323-2330. https://doi.org/10.1016/j.ejmech.2007.10.012

Tribak Z, Skalli MK, Senhaji O. A Review on Recent Advances and Applications of 5-Chloroisatin and its Derivatives in Design and Synthesis of New Organic Compounds. American International Journal of Research in Formal, Applied & Natural Sciences 2017;19:41–50.

Tribak Z, Chda A, Skalli M, Haoudi A, Rodi Y, Senhaji O, Essassi E, Cheikh R, El Abida K. Theoretical approach using DFT and muscle relaxant effects of 5-Chloroisatin Derivatives. International Journal of Chemistry and Technology 2018;2(2):105-115. https://doi.org/10.32571/ijct.446539

Tribak Z, Skalli MK, Senhaji O. Anticorrosion Activity for Some 5-Chloroisatin Derivatives. Editions Universitaires Européennes 2017;1–46.

Tribak Z, Kandri Rodi Y, Haoudi A, Essassi E, Capet F, Zouihri H. 5-Chloro-1-methylindoline-2,3-dione. IUCrData 2016;1(6):x160913. https://doi.org/10.1107/s2414314616009135

Tribak Z, Kandri Rodi Y, Haoudi A, Essassi E, Capet F, Zouihri H. 1-Benzyl-5-chloroindoline-2,3-dione. IUCrData 2016;1(6):x160854. https://doi.org/10.1107/s2414314616008543

Tribak Z, Kandri Rodi Y, Haoudi A, Essassi E, Capet F, Zouihri H. 1-Allyl-5-chloroindoline-2,3-dione. IUCrData 2016;1(6):x160862. https://doi.org/10.1107/s2414314616008622

Tribak Z, Kandri Rodi Y, Haoudi A, Essassi E, Capet F, Zouihri H. 1-(12-Bromododecyl)-5-chloroindoline-2,3-dione. IUCrData 2016;1(6):x160971. https://doi.org/10.1107/s2414314616009718

Tribak Z, Ghibate R, Skalli M. Experimental and Theoretical Study for Corrosion Inhibition in 1M HCl Solution by New 5-Chloroisatin Derivative. Int. J. sci. Technol. Eng. 2016;3:257-262.

Tribak Z, Haoudi A, Rodi Kandri Y. Synthesis and reactivity of new heterocyclic systems derived from 5-chloro- 1H-indole-2,3-dione. Moroccan Journal of Chemistry 2016;4:1157–1163.

Tribak Z, Kharbach Y, Haoudi A. Study of new 5-Chloro-Isatin derivatives as efficient organic inhibitors of corrosion in 1M HCl medium: Electrochemical and SEM studies. Journal of Materials and Environmental Science 2016;7:2006–2020.

Tribak Z, Kandri Rodi Y, Elmsellem H. The roles of 1-allyl-5-chloro-indoline-2, 3-dione on the corrosion inhibition of steel in HCl media. Moroccan Journal of Heterocyclic Chemistry 2017;16:157–165.

Tribak Z, Haoudi A, Skalli MK. 5-Chloro-1H-indole-2,3-dione derivative as corrosion inhibitor for mild steel in 1M H3PO4: Weight loss, electrochemical and SEM studies. Journal of Materials and Environmental Science 2017;8:299–309.

Tribak Z, Kandri Rodi Y, Elmsellem H. 5-Chloro-1-Octylindoline-2,3-Dione As a New Corrosion Inhibitor for Mild Steel in Hydrochloric Acid Solution. Journal of Materials and Environmental Science 2017;8:1116–1127.

Obot I, Obi-Egbedi N, Umoren S. Adsorption Characteristics and Corrosion Inhibitive Properties of Clotrimazole for Aluminium Corrosion in Hydrochloric Acid. International Journal of Electrochemical Science 2009;4(6):863-877. https://doi.org/10.1016/s1452-3981(23)15190-x

Rubaye A, Abdulsahib H, Abdulwahid A. Corrosion Inhibition Properties of Norepinephrine Molecules on Mild Steel in Acidic Media. Journal of Encapsulation and Adsorption Sciences 2015;05(03):155-164. https://doi.org/10.4236/jeas.2015.53013

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Published

2026-07-29

Issue

Vol. 14 No. 1 (2026)

Section

Review

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