Kinetic study of carbon dioxide catalytic methanation over cobalt–nickel catalysts

Alla G. Dyachenko; Olena V. Ischenko; Snizhana V. Gaidai; Tetiana M. Zakharova; Andrii V. Yatsymyrskyi; Vladyslav V. Lisnyak

doi:10.17721/fujcV7I1P74-80

Authors

Alla G. Dyachenko Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0002-0955-5040
Olena V. Ischenko Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0001-9782-1769
Snizhana V. Gaidai Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0001-7742-5830
Tetiana M. Zakharova Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0003-2291-157X
Andrii V. Yatsymyrskyi Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0001-5050-8281
Vladyslav V. Lisnyak Department of Chemistry, Taras Shevchenko National University of Kyiv http://orcid.org/0000-0002-6820-1445

DOI:

https://doi.org/10.17721/fujcV7I1P74-80

Keywords:

Sabatier process, bimetallic catalysts, catalytic methanation of CO2, kinetic patterns

Abstract

Based on the data of the thermoprogrammed desorption and using mass-spectroscopic analysis of desorbed products and on the kinetic patterns of the methanation process for cobalt–nickel catalysts, we suggested a mechanism for the reaction which passes through forming intermediate formyl compounds: CHO*, HCOH*, and HCOOH*. Because of the high stability of the carbon dioxide molecule, the step of adding the first hydrogen atom is the limiting step. Such a mechanism is in good agreement with the proposed kinetic equations.

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Kinetic study of carbon dioxide catalytic methanation over cobalt–nickel catalysts

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