The Sensitization of Aliphatic Epoxy Photopolymerization in Epoxy-Acrylate Interpenetrating Polymer Networks
DOI:
https://doi.org/10.17721/fujcV2I1P5-9Keywords:
cationic photopolymerization, free-radical-promoted cationic polymerization process, photosensitization, aliphatic epoxy resin, epoxy-acrylate interpenetrating polymer networksAbstract
The paper discuses the phenomenon of the sensitization of the aliphatic epoxy photopolymerization in the presence of acrylate oligomers while forming epoxy-acrylate interpenetrating polymer networks. The photopolymerization process was studied by IR spectroscopy and the properties of the final products – by the Gardner test, crosshatch adhesion test, and the pencil hardness test. The epoxy groups conversion, which is rather low in aliphatic epoxy polymers, was found to alter with the increase of acrylate compounds content. The materials synthesized on the base of interpenetrating polymer networks were shown to reveal fine properties and may have a potential application as coatings.
References
Decker C, Nguyen Thi Viet T, Decker D, Weber-Koehl E. UV-radiation curing of acrylate/epoxide systems. Polymer 2001;42(13):5531-5541. https://doi.org/10.1016/s0032-3861(01)00065-9
Hua Y, Crivello J. Synergistic interaction of epoxides andN-vinylcarbazole during photoinitiated cationic polymerization. J. Polym. Sci. A Polym. Chem. 2000;38(19):3697-3709. https://doi.org/10.1002/1099-0518(20001001)38:19<3697::aid-pola240>3.0.co;2-b
Tehfe M, Lalevée J, Gigmes D, Fouassier J. Green Chemistry: Sunlight-Induced Cationic Polymerization of Renewable Epoxy Monomers Under Air. Macromolecules 2010;43(3):1364-1370. https://doi.org/10.1021/ma9025702
Menzheres GI, Diadiusha AG, Vatuliov VN et al. Jurn. prikl. himii 1989;62(10):2348-2352.
Kligshtein M, Menzheres G, Degtyareva A, Vatylev V, Magdinets V. Behaviour of a sulphonium salt on photo-initiated oligomerization of propylene oxide. Polymer Science U.S.S.R. 1991;33(5):886-892. https://doi.org/10.1016/0032-3950(91)90153-h
Bulut U, Crivello J. Investigation of the Reactivity of Epoxide Monomers in Photoinitiated Cationic Polymerization. Macromolecules 2005;38(9):3584-3595. https://doi.org/10.1021/ma050106k
Lalevée J, Fouassier J. Recent advances in sunlight induced polymerization: role of new photoinitiating systems based on the silyl radical chemistry. Polym. Chem. 2011;2(5):1107. https://doi.org/10.1039/c1py00073j
Samoilenko TF, Brovko OO, Iarova NV, Polimernyi jurnal, 2014;36(1):66-77.
Brovko OO, Honcharova LA, Shtompel VI et al. Polimernyi jurnal 2005;27(1):45-50.
Samoilenko TF, Brovko OO, Iarova NV, Menzheres GI et al. ХІІІ Ukraiins’ka konferentsiia z VMS, m. Kyiiv, 2013:290-292.
Cai Y, Jessop J. Decreased oxygen inhibition in photopolymerized acrylate/epoxide hybrid polymer coatings as demonstrated by Raman spectroscopy. Polymer 2006;47(19):6560-6566. https://doi.org/10.1016/j.polymer.2006.07.031
Crivello J, Lam J. Triarylsulfonium salts as photoinitiators of free radical and cationic polymerization. Journal of Polymer Science: Polymer Letters Edition 1979;17(12):759-764. https://doi.org/10.1002/pol.1979.130171203
Batoh OP, Chaiko AK, Vatuliov NV et al. Kompozyts. polimer. materialy 1999;21(1):41-45.
Lecamp L, Pavillon C, Lebaudy P, Bunel C. Influence of temperature and nature of photoinitiator on the formation kinetics of an interpenetrating network photocured from an epoxide/methacrylate system. European Polymer Journal 2005;41(1):169-176. https://doi.org/10.1016/j.eurpolymj.2004.09.003
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