In situ polymerization of 4-(methacryloylamino) phenyl-2-methylacrylate on the surface of silicagel

Authors

  • Elina Yanovska Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Lyudmyla Vretik Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Dariusz Sternik Maria Curie-Skłodowska University, 2 Maria Curie-Skłodowska Sq., 20 031 Lublin, Poland
  • Olga Kychkiruk Department of Sciences, Ivan Franko Zhytomyr State University, 40 Velyka Berdychivska St., 10008 Zhytomyr, Ukraine
  • Olena Nikolaeva Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine
  • Iana Buriachenko Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine

DOI:

https://doi.org/10.17721/fujcV4I2P47-54

Keywords:

phenylmethylacrylate, modified silica, in situ immobilization, metal complexes, adsorption properties

Abstract

Immobilization of 4-(methacryloylamino)phenyl-2-methylacrylate homopolymer on the silica gel surface has been carried out in situ. The structure and quantitative characteristics of immobilized polymer have been examined by IR spectroscopy, thermogravimetric analysis and mass spectrometry. Adsorption activity towards microquantitatives of Pb(II), Cu (II), Mn(II), Co(II), Ni(II) and Fe(III) ions in the range of pH 6-8,5 has been observed. Quantitative adsorption of trace Pb(II) in neutral and slightly alkaline media has been reported.

Author Biography

Lyudmyla Vretik, Chemistry Department, Taras Shevchenko National University of Kyiv, 12 L. Tolstogo St., 01033 Kyiv, Ukraine

Chemistry department

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Published

2016-12-27

Issue

Vol. 4 No. 2 (2016)

Section

Articles

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